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A Set of bronze sculpture statue of Ming Dynasty

Bronze ware has an excellent historical value, artistic value and scientific value. However, owning to the fact that it has been buried under ground for a long time as well as the limitation of storage constraints after being unearthed, ancient bronze ware faces a severe problem of corrosion protection. Transition period of the bronze sculpture statue generally refers to the period between the late Warring States and late Qin and Han Dynasty. The corrosion of bronze ware is briefly reviewed, the research methods, corrosion mechanism and protection methods of bronze ware are deeply described. Finally, research trends in the protections of the bronzes are analyzed.
Unearthed bronze relics often buried in the ground before a few hundred or even thousands of years, will have varying degrees of damage and corrosion, bronze disease is the most harmful of which a special kind of corrosion. The traditional ritual system has been complete collapsed resulting in the disappearance of the bronze sculpture statue. Once infected with bronze statue disease, its spread and development will be difficult to control, ranging from the surface caused by the bronze inscriptions, patterns and other important historical archaeological heritage value of the information is destroyed leaving serious damage. Perforated ulcers while in the objects or even complete disintegration. So. Corrosion of bronze in the study, based on the principles, how to conduct scientific bronze relics protection an important issue currently facing.
Bronze is an alloy, the main ingredient is copper, tin, lead, and contains very small amounts of iron, nickel, zinc, manganese, silicon, arsenic and phosphorus. Chinese Bronze Age bronze artifacts, the composition of tin bronze and lead bronze main '21. From the thermodynamic point of view, this component determines the energy position of the metallic bronze will eventually be spontaneously converted to low-energy position of the compound state of ore, that is, that bronze corrosion is a natural, spontaneous process. In this stage, the role of the bronze sculpture statue played in the society started to decline little by little. Relatively suitable conditions (such as low temperature, low humidity, no UV irradiation, no harmful gases, etc.), the bronze corrosion layers generally remained stable.
 If the environment changes, especially by the temperature, humidity, very prone to rust and bronze powder. FITZGERALD and others on the atmospheric corrosion of copper in different regions were studied, the impact that the external environment is an important factor leading to corrosion of chinese bronze. Most vessels are classified to daily bronze sculpture statue. Therefore, the bronze artifacts unearthed by the hypoxic environment before entering the oxygen-rich environment unearthed after this change is the main reason leading to corrosion. Bronze artifacts unearthed a large number of surface corrosion products usually attached to these harmful rust corrosion products can be divided into two major categories of rust and harmless.
Harmless rust can increase the artistic value of bronze artifacts, and to play a protective role. Rust is harmless bronze buried by flooding and erosion of the atmosphere, the bronze surface changes, which form the protective layer, so that artifacts can not continue to suffer corrosion. But if narrow it down to certain bronze sculpture statue, there were quite a few fancy artworks. Its chemical composition includes black copper oxide (CuO), the red cuprous oxide (Cu: O), green or blue-green basic copper carbonate (green copper CuC03 ? Cu (OH) 2, azurite 2CuC03 ? Cu (OH) 2), sometimes mixed with black copper sulfide (CuS), white tin oxides. These are china bronze rust in a stable, rich colors, the composition of the formation of fine old spot.
related bronze sculpture statue:
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